Lanthanide doped nanocrystals with strong fluorescence, long lifetime at high doping concentrations have great potential application in bio-imaging and liquid gain medium. LiNd（PO3）4（LNP） crystal was reported to be one of the most excellent laser crystals with high Nd3+ concentration, and their nanocrystals synthesized via improved combustion method for the first time had strong emission intensity and long fluorescence lifetime of 122 μs. Besides,LiNd（PO3）4 nanocrystals can be dispersed in mixed solvents of DMSO/TBE（CHBr2 CHBr2） to form a transparent colloidal dispersion, and Judd-Ofelt theory was used to evaluate their optical parameters. In summary, LiNd（PO3）4 nanocrystals possess long lifetime（116 μs）, low solvents quenching rate（4.9%）, large emission cross section(7.63 × 10-20cm2) and high quantum yield（35.2%） under high Nd3+ ions concentration(1×1020cm-3), which would be the most competitive colloidal gain medium of optical amplification and laser with LD pump and potential biomaterial with low particles concentration.
类型: 期刊论文
作者: Zhongyue Wang,Zhen Yang,Ruilin Zheng,Kehan Yu,Peng Lv,Chunxiao Liu,Wei Wei
来源: Journal of Rare Earths 2019年06期
年度: 2019
分类: 工程科技Ⅰ辑
专业: 有机化工
单位: College of Electronic and Optical Engineering & College of Microelectronics (EOM),Nanjing University of Posts and Telecommunications (NUPT)
基金: Project supported by the National Natural Science Foundation of China(51502144,61504064,51503102),the Scientific Research Foundation of Nanjing University of Posts and Telecommunications(NY214163)
分类号: TQ422
页码: 580-584
总页数: 5
文件大小: 703K
下载量: 5
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