The Effect of Reaction Conditions on the Synthesis of Thermoplastic Elastomers Containing Polyalloocimene, Polyisobutylene and Tapered Blocks

论文摘要

This work investigates the effect of reaction conditions on the copolymerization of isobutylene（IB） with alloocimene（Allo） in methyl chloride（MeCl） using AlCl3 and ethylaluminum dichloride（EtAlCl2） as coinitiators and adventitious moisture as the initiator.Both AlCl3 and EtAlCl2 produced high molecular weight（Mn > 1.0 × 105 g/mol） thermoplastic elastomers（TPEs） with good mechanical properties in short reaction time（< 10 min）. These unique TPEs have unsaturations in the end blocks, leading to easy functionalization and/or crosslinking.

论文目录

文章来源

类型: 期刊论文

作者: Jozsef Kantor,Judit E.Puskas,Gabor Kaszas

来源: Chinese Journal of Polymer Science 2019年09期

年度: 2019

分类: 工程科技Ⅰ辑

专业: 有机化工

单位: Department of Chemical and Biomolecular Engineering, The University of Akron,Department of Food, Agricultural and Biological Engineering (1/1/2019), The Ohio State University

基金: financially supported by the National Science Foundation (No. IIP-1434014) (Accelerating Innovation Research),Support by the Breast Cancer Innovation Foundation was also acknowledged

分类号: TQ334

页码: 884-890

总页数: 7

文件大小: 707K

下载量: 4

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