A review of recent researches on Bunsen reaction for hydrogen production via S–I water and H2S splitting cycles

论文摘要

The Bunsen reaction is the center reaction for both the sulfur–iodine water splitting cycle for hydrogen production and the novel hydrogen sulfide splitting cycle for hydrogen and sulfuric acid production from the sulfur-containing gases.This paper reviews the research progress of the Bunsen reaction in recent 10–15 years.Researches were initially focused on the optimization of the operating conditions of the conventional Bunsen reaction requiring excessive water and iodine to improve the products separation efficiency and to avoid the side reactions and iodine vapor deposition.Alternative methods including electrochemical methods,precipitation methods,and non-aqueous solvent methods had their respective advantages,but still faced challenges.In development of the technology of H2S splitting cycle,dissolving iodine in toluene solvent could render the Bunsen reaction to occur with the flowable I2 stream at ambient temperature such that the side reactions and iodine vaporization can be avoided and the corrosion hazard lessened.It also prevented the Bunsen reaction from using excessive iodine and water.The products from the Bunsen reaction including HI,H2SO4,H2O,and toluene could be directly electrolyzed.

论文目录

文章来源

类型: 期刊论文

作者: Ke Zhang,Weiren Bao,Liping Chang,Hui Wang

来源: Journal of Energy Chemistry 2019年06期

年度: 2019

分类: 工程科技Ⅰ辑

专业: 无机化工

单位: Key Laboratory of Coal Science and Technology of Ministry of Education and Shanxi Province, Taiyuan University of Technology,Department of Chemical and Biological Engineering, University of Saskatchewan

基金: financial supports from the National Natural Science Foundation of China (21576183),Natural Science and Technology Research Council of Canada (STPGP-350428-07)

分类号: TQ116.2

页码: 46-58

总页数: 13

文件大小: 2329K

下载量: 8

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