Hydrothermal Synthesis, Crystal Structure and Properties of a New Copper Coordination Polymer [Cu2I（C7H5N4）2]n with 3-（Pyridin-2-yl）-1,2,4-triazole) Ligand

论文摘要

A new copper coordination polymer [Cu2I（C7H5N4）2]n（1） with the 3-（pyridin-2-yl）-1,2,4-triazole（Hpt） and copper iodide was synthesized. It crystallizes in the triclinic space group P1 with a = 8.6380（9）, b = 9.2434（9）, c = 11.8588（12） ?, α = 99.5890（10）o, β = 109.0990（10）o, γ = 105.2800（10）o, V = 829.25（15） ?3, Dc = 2.180 g/cm3, Z = 2, F（000） = 522, GOOF = 1.046, the final R = 0.0245 and wR = 0.0598. The crystal structure shows that two copper ions are bridged by two μ2-η1:η0-3-（pyridin-2-yl）-1,2,4-triazole anions and two iodide ions. The coordination environments of the Cu ion are Cu（1）N5 and Cu（2）N2I2, giving distorted square pyramidal geometry and trigon pyramid geometry. The magnetic and fluorescent properties of 1 were studied.

论文目录

1 INTRODUCTION

2 EXPERIMENTAL

2.1 Materials and instrumentation

2.2 Synthesis of 1

2.3 Determination of the crystal structure

3 RESULTS AND DISCUSSION

3.1 Crystal structure of 1

3.2 Magnetic properties of 1

3.3 Fluorescence of 1

4 CONCLUSION

文章来源

类型: 期刊论文

作者: 颜佳佳,李昶红,李薇,杨紫豚,李玲,刘荷葆

来源: Chinese Journal of Structural Chemistry 2019年10期

年度: 2019

分类: 工程科技Ⅰ辑

专业: 化学

单位: Hengyang Normal University,School of Materials and Chemical Engineering, Hunan Institute of Technology

基金: Supported by the Natural Science Foundation of Hunan Province(2019JJ60021),the Scientific Research Found of Hunan Provincial Education Department of China(17A049),Industry and Research Key Project of Hengyang City(2018k KJ016,2017KJ155,2017KJ193)

分类号: O641.4

DOI: 10.14102/j.cnki.0254-5861.2011-2336

页码: 1823-1827

总页数: 5

文件大小: 371K

下载量: 22

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Hydrothermal Synthesis, Crystal Structure and Properties of a New Copper Coordination Polymer [Cu2I（C7H5N4）2]n with 3-（Pyridin-2-yl）-1,2,4-triazole) Ligand

论文摘要

论文目录

文章来源

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