论文摘要
Cobalt and nitrogen codoped carbon materials（Co-N-C） were fabricated by pyrolysis of the mixture of poly（4-vinylpyridine） and cobalt chloride using SiO2 nanoparticles as hard template, which were the first transition metal/nitrogen-codoped carbon bifunctional electrocatalyst derived from noncarbonizable polymer for ORR and HER. The as-made Co-N-C possessed hierarchical pore structure and high specific surface area, achieving excellent electrocatalytic performances for ORR and HER. Its ORR catalytic performances were comparable to those of Pt/C catalyst and its HER catalytic performances were superior to those of most doped carbon catalysts in KOH electrolyte. Moreover, its bifunctional electrocatalytic performances for ORR and HER were better than those of most bifunctional doped carbon catalysts in alkaline electrolyte.
论文目录
文章来源
类型: 期刊论文
作者: Xiaoxia Chen,Xiangjun Zhen,Hongyu Gong,Le Li,Jianwei Xiao,Zhi Xu,Deyue Yan,Guyu Xiao,Ruizhi Yang
来源: Chinese Chemical Letters 2019年03期
年度: 2019
分类: 工程科技Ⅰ辑
专业: 化学
单位: School of Chemistry and Chemical Engineering,State Key Laboratory of Metal Matrix Composites, Shanghai Jiao Tong University,College of Physics, Optoelectronics and Energy & Collaborative Innovation Center of Suzhou Nano Science and Technology, Soochow University
基金: supported by the National Natural Science Foundation of China(Nos.21774073,51690151,21404071,and 21320102006),the National Basic Research Program (No. 2016YFA0201500)
分类号: O643.36
页码: 681-685
总页数: 5
文件大小: 1081K
下载量: 15