Thermoresponsive Fluorescent Semicrystalline Polymers Decorated with Aggregation Induced Emission Luminogens

Thermoresponsive Fluorescent Semicrystalline Polymers Decorated with Aggregation Induced Emission Luminogens

论文摘要

Thermoresponsive fluorescent polymers(TFPs) with unique temperature-dependent luminescent properties are of great importance for the development of new functional devices in recent years. Herein, we facilely synthesized an efficient blue-emissive polymer, abbreviated as PCB-TPE, using tetraphenylethene(TPE) as the main building block. PCB-TPE is thermally stable with a novel property of aggregation induced emission(AIE). The thermoresponsive property and mechanism of PCB-TPE were investigated. Its emission shows temperature-dependent features and reveals fine details in the thermal transitions from-10 °C to 60 °C. The polymer offers a platform for the development of efficient luminescent materials for further biological and optoelectronic applications.

论文目录

  • INTRODUCTION
  • EXPERIMENTAL
  •   Materials
  •   Synthesis of 2-Bromomethyl-2-methyltrimethylene Carbonate (BMTC)
  •   Synthesis of Copolymer ofε-CL and BMTC (PCB)
  •   Post-decoration of PCB with Tetraphenylethene (PCB-TPE)
  •   Characterization
  • RESULTS AND DISCUSSION
  • CONCLUSIONS
  • 文章来源

    类型: 期刊论文

    作者: Jia-Long Wu,Chi Zhang,Wei Qin,Da-Ping Quan,Ming-Liang Ge,Guo-Dong Liang

    来源: Chinese Journal of Polymer Science 2019年04期

    年度: 2019

    分类: 工程科技Ⅰ辑

    专业: 化学

    单位: PCFM and GDHPPC labs,School of Materials Science and Engineering,Sun Yat-sen University,School of Chemistry,Sun Yat-sen University,Key Laboratory of Polymer Processing Engineering,South China University of Technology,Ministry of Education

    基金: financially supported by the National Natural Science Foundation of China (No. 21374136),the Fundamental Research Funds for the Central Universities (Nos. 17lgjc03 and 18lgpy04),the Opening Project of the Key Laboratory of Polymer Processing Engineering (South China University of Technology,Ministry of Education,No. KFKT1703)

    分类号: O631.24

    页码: 394-400

    总页数: 7

    文件大小: 772K

    下载量: 31

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