论文摘要
A new 2D coordination polymer, {[Cd5（BTC）2（L）4（H2O）2]n·2H2O}n（1, H3BTC = 1,3,5-benzenetricarboxylic acid, HL = 3-（2-pyridyl）pyrazole） was synthesized under hydrothermal conditions and characterized by single-crystal X-ray diffraction, powder XRD, IR, TGA, fluorescence spectrum and elemental analysis techniques. Complex 1 belongs to the monoclinic system, P21/c space group, with a = 8.8732（4）, b = 17.5179（7）, c = 17.8123（7） ?, β = 103.1830（10）°, V = 2695.77（19） ?3 and Z = 2. It features a 2D network constructed by BTC and L ligand. In addition, we analyzed Natural Bond Orbital（NBO） by using the PBE0/LANL2DZ method built in Gaussian 09 Program. The calculation results indicated obvious covalent interactions between the coordinated atoms and Cd（Ⅱ） ion.
论文目录
文章来源
类型: 期刊论文
作者: 王秀艳,李秀梅,潘亚茹,刘博,周实
来源: Chinese Journal of Structural Chemistry 2019年08期
年度: 2019
分类: 工程科技Ⅰ辑
专业: 化学
单位: Key Laboratory of Preparation and Applications of Environmental Friendly Materials (Jilin Normal University), Ministry of Education,Faculty of Chemistry, Tonghua Normal University
基金: supported by the Science and Technology development plan of Jilin Province(2015052006JH)
分类号: O641.4
DOI: 10.14102/j.cnki.0254-5861.2011-2220
页码: 1275-1282
总页数: 8
文件大小: 627K
下载量: 16
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